Californium in PDB 5kic: Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series

The structure of Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series, PDB code: 5kic was solved by P.B.Rupert, R.K.Strong, with X-Ray Crystallography technique. A brief refinement statistics is given in the table below:

Resolution Low / High (Å)	50.00 / 2.70
Space group	P 41 21 2
Cell size a, b, c (Å), α, β, γ (°)	119.574, 119.574, 108.839, 90.00, 90.00, 90.00
R / Rfree (%)	20.5 / 24.2

The structure of Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series also contains other interesting chemical elements:

Chlorine

(Cl)

3 atoms

The binding sites of Californium atom in the Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series (pdb code 5kic). This binding sites where shown within 5.0 Angstroms radius around Californium atom.
In total 3 binding sites of Californium where determined in the Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series, PDB code: 5kic:
Jump to Californium binding site number: 1; 2; 3;

Californium binding site 1 out of 3 in the Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series


Mono view


Stereo pair view

A full contact list of Californium with other atoms in the Cf binding site number 1 of Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series within 5.0Å range: probe atom residue distance (Å) B Occ A:Cf201 b:0.2 occ:1.00 O10 A:4OL202 2.2 93.5 1.0 O47 A:4OL202 2.8 93.7 1.0 O46 A:4OL202 2.8 0.1 1.0 O9 A:4OL202 3.0 69.8 1.0 N3 A:4OL202 3.2 76.1 1.0 O50 A:4OL202 3.2 1.0 1.0 C4 A:4OL202 3.5 72.6 1.0 C36 A:4OL202 3.6 90.7 1.0 O48 A:4OL202 3.6 0.8 1.0 N35 A:4OL202 3.7 95.1 1.0 O51 A:4OL202 3.7 93.7 1.0 N45 A:4OL202 3.8 0.6 1.0 NZ A:LYS125 3.8 70.9 1.0 C44 A:4OL202 4.0 0.5 1.0 NZ A:LYS134 4.1 52.6 1.0 CE A:LYS125 4.2 64.9 1.0 C2 A:4OL202 4.4 79.2 1.0 N9 A:4OL202 4.6 96.8 1.0 CZ3 A:TRP79 4.7 81.8 1.0 CH2 A:TRP79 4.8 82.3 1.0 C5 A:4OL202 4.8 71.2 1.0 C40 A:4OL202 4.8 0.8 1.0 C37 A:4OL202 4.9 89.8 1.0 C1 A:4OL202 4.9 82.4 1.0 OH A:TYR106 4.9 53.4 1.0 C14 A:4OL202 4.9 1.0 1.0

Californium binding site 2 out of 3 in the Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series


Mono view


Stereo pair view

A full contact list of Californium with other atoms in the Cf binding site number 2 of Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series within 5.0Å range: probe atom residue distance (Å) B Occ B:Cf201 b:0.3 occ:1.00 O10 B:4OL202 2.3 0.8 1.0 O46 B:4OL202 2.7 1.0 1.0 O50 B:4OL202 3.0 0.9 1.0 O47 B:4OL202 3.1 90.0 1.0 O9 B:4OL202 3.3 75.7 1.0 O51 B:4OL202 3.3 91.9 1.0 N3 B:4OL202 3.3 87.1 1.0 N35 B:4OL202 3.7 0.0 1.0 C4 B:4OL202 3.7 80.9 1.0 N45 B:4OL202 3.7 0.3 1.0 C36 B:4OL202 3.8 96.0 1.0 O48 B:4OL202 3.8 0.1 1.0 C44 B:4OL202 3.8 0.5 1.0 NZ B:LYS125 4.0 71.5 1.0 NZ B:LYS134 4.1 67.9 1.0 CE B:LYS125 4.4 67.7 1.0 C2 B:4OL202 4.5 89.5 1.0 N9 B:4OL202 4.6 0.5 1.0 C14 B:4OL202 4.6 0.8 1.0 CZ3 B:TRP79 4.7 80.2 1.0 O54 B:4OL202 4.8 0.5 1.0 OH B:TYR106 4.9 55.9 1.0 N32 B:4OL202 4.9 0.3 1.0 C1 B:4OL202 4.9 92.7 1.0 CH2 B:TRP79 4.9 79.8 1.0 C40 B:4OL202 4.9 0.8 1.0 C34 B:4OL202 5.0 0.9 1.0 C5 B:4OL202 5.0 83.2 1.0

Californium binding site 3 out of 3 in the Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series


Mono view


Stereo pair view

A full contact list of Californium with other atoms in the Cf binding site number 3 of Long-Sought Stabilization of Berkelium(IV) in Solution: An Anomaly Within the Heavy Actinide Series within 5.0Å range: probe atom residue distance (Å) B Occ C:Cf201 b:0.4 occ:1.00 O10 C:4OL202 2.2 82.0 1.0 O46 C:4OL202 2.7 96.7 1.0 O47 C:4OL202 2.9 88.6 1.0 O50 C:4OL202 2.9 0.5 1.0 O9 C:4OL202 3.1 74.1 1.0 N3 C:4OL202 3.1 77.9 1.0 O51 C:4OL202 3.1 0.4 1.0 O48 C:4OL202 3.2 94.7 1.0 C4 C:4OL202 3.5 76.9 1.0 N35 C:4OL202 3.6 88.0 1.0 C36 C:4OL202 3.6 85.8 1.0 N45 C:4OL202 3.7 0.0 1.0 C44 C:4OL202 3.7 0.7 1.0 NZ C:LYS125 3.9 57.9 1.0 NZ C:LYS134 4.1 52.2 1.0 C2 C:4OL202 4.3 80.7 1.0 CE C:LYS125 4.3 54.0 1.0 O49 C:4OL202 4.4 0.5 1.0 N9 C:4OL202 4.5 98.2 1.0 N27 C:4OL202 4.5 0.3 1.0 C5 C:4OL202 4.8 76.6 1.0 C1 C:4OL202 4.8 89.1 1.0 CZ3 C:TRP79 4.8 68.7 1.0 C37 C:4OL202 4.9 87.2 1.0 C34 C:4OL202 4.9 91.0 1.0 C40 C:4OL202 4.9 0.3 1.0 N32 C:4OL202 4.9 0.6 1.0 C29 C:4OL202 4.9 95.1 1.0 C43 C:4OL202 5.0 0.9 1.0 C26 C:4OL202 5.0 0.2 1.0 CH2 C:TRP79 5.0 69.4 1.0

G.J.Deblonde, M.Sturzbecher-Hoehne, P.B.Rupert, D.D.An, M.C.Illy, C.Y.Ralston, J.Brabec, W.A.De Jong, R.K.Strong, R.J.Abergel. Chelation and Stabilization of Berkelium in Oxidation State +IV. Nat Chem V. 9 843 2017.
ISSN: ESSN 1755-4349
PubMed: 28837177
DOI: 10.1038/NCHEM.2759